Now showing items 21-40 of 40

    • Methane transport and sources in an Arctic deep-water cold seep offshore NW Svalbard (Vestnesa Ridge, 79°N) 

      Sauer, Simone; Hong, Wei-Li; Yao, Haoyi; Lepland, Aivo; Klug, Martin; Eichinger, Florian; Himmler, Tobias; Cremiere, Antoine; Panieri, Giuliana; Schubert, Carsten J.; Knies, Jochen (Journal article; Tidsskriftartikkel; Peer reviewed, 2020-10-29)
      We investigate the uppermost 60 cm of sediment in active pockmarks of a deep-water methane seep site from Vestnesa Ridge offshore NW Svalbard. Using video guided core sampling with a remotely operated vehicle we collected push cores directly from bacterial mats within two active pockmarks, Lunde and Lomvi. Pore water analyses show very shallow sulphate methane transition zones and transport-reaction ...
    • Multiple sulfur isotopes in methane seep carbonates track unsteady sulfur cycling during anaerobic methane oxidation 

      Cremiere, Antoine; Pellerin, André; Wing, Boswell A.; Lepland, Aivo (Journal article; Tidsskriftartikkel; Peer reviewed, 2019-12-19)
      The anaerobic oxidation of methane coupled with sulfate reduction (AOM-SR) is a major microbially-mediated methane consuming process in marine sediments including methane seeps. The AOM-SR can lead to the formation of methane-derived authigenic carbonates which entrap sulfide minerals (pyrite) and carbonate-associated sulfate (CAS). We studied the sulfur isotope compositions of the pyrite and CAS ...
    • Multiple sulphur isotope records tracking basinal and global processes in the 1.98 Ga Zaonega Formation, NW Russia 

      Paiste, Kärt; Lepland, Aivo; Zerkle, A.L.; Kirsimäe, Kalle; Izon, G.; Patel, N.K.; McLean, F.; Kreitsmann, T.; Mänd, Kaarel; Bui, T.H.; Romashkin, Alexander E.; Rychanchik, Dimitry V.; Prave, Anthony R (Journal article; Tidsskriftartikkel; Peer reviewed, 2018-09-19)
      The exceptionally organic-rich rocks of the 1.98 Ga Zaonega Formation deposited in the Onega Basin, NW Russia, have refined our understanding of Earth System evolution during the Paleoproterozoic rise in atmospheric oxygen. These rocks were formed in vent- or seep influenced settings contemporaneous with voluminous mafic volcanism and contain strongly <sup>13</sup>C-depleted organic matter. ...
    • New cold seep sites on the continental slope southwest to Svalbard 

      Bellec, Valerie Karin; Chand, Shyam; Knies, Jochen Manfred; Bjarnadóttir, Lilja Rún; Lepland, Aivo; Sen, Arunima; Thorsnes, Terje (Journal article; Tidsskriftartikkel; Peer reviewed, 2024-04-09)
      We discovered seafloor features such as bacterial mats and carbonate crusts typical for active methane seeps on the continental slope southwest of Svalbard. These features are associated with two main northwest-southeast trending morphological structures that are oriented parallel to the regional continental slope. Both structures occur at c. 800 m water depth, at the boundary between the Storfjorden ...
    • Origin and transformation of light hydrocarbons ascending at an active pockmark on Vestnesa Ridge, Arctic Ocean 

      Pape, Thomas; Buenz, Stefan; Hong, Wei-Li; Torres, Marta E.; Riedel, Matthias; Panieri, Giuliana; Lepland, Aivo; Hsu, Chieh Wei; Wintersteller, Paul; Wallmann, Klaus; Schmidt, Christopher; Yao, Haoyi; Bohrmann, Gerhard (Journal article; Tidsskriftartikkel; Peer reviewed, 2019-10-25)
      We report on the geochemistry of hydrocarbons and pore waters down to 62.5 mbsf, collected by drilling with the MARUM‐MeBo70 and by gravity coring at the Lunde pockmark in the Vestnesa Ridge. Our data document the origin and transformations of volatiles feeding gas emissions previously documented in this region. Gas hydrates are present where a fracture network beneath the pockmark focusses migration ...
    • Oxygenated conditions in the aftermath of the Lomagundi-Jatuli Event: The carbon isotope and rare earth element signatures of the Paleoproterozoic Zaonega Formation, Russia 

      Kreitsmann, T.; Lepland, Aivo; Bau, M.; Prave, A.R.; Paiste, Kärt; Mänd, K.; Sepp, H.; Martma, T.; Romashkin, A.E; Kirsimäe, K. (Journal article; Tidsskriftartikkel; Peer reviewed, 2020-07-09)
      The c. 2.0 Ga Zaonega Formation of the Onega Basin (NW Russia) has been central in efforts to understand what led to the initial rise (Great Oxidation Event, GOE) and postulated fall in free atmospheric oxygen and associated high-amplitude carbon cycle excursions, the Lomagundi-Jatuli Event (LJE) and subsequent Shunga Event during Paleoproterozoic time. The Formation accumulated shortly after the ...
    • Palaeoproterozoic oxygenated oceans following the Lomagundi–Jatuli Event 

      Mänd, Kaarel; Lalonde, Stefan V.; Robbins, Leslie J.; Thoby, Marie; Paiste, Kärt; Kreitsmann, Timmu; Paiste, Päärn; Reinhard, Christopher T.; Romashkin, Alexandr E.; Planavsky, Noah J.; Kirsimäe, Kalle; Lepland, Aivo; Konhauser, Kurt O. (Journal article; Tidsskriftartikkel; Peer reviewed, 2020-03-16)
      The approximately 2,220–2,060 million years old Lomagundi–Jatuli Event was the longest positive carbon isotope excursion in Earth history and is traditionally interpreted to reflect an increased organic carbon burial and a transient rise in atmospheric O<sub>2</sub>. However, it is widely held that O<sub>2</sub> levels collapsed for more than a billion years after this. Here we show that black shales ...
    • Protracted post-glacial hydrocarbon seepage in the Barents Sea revealed by U–Th dating of seep carbonates 

      Himmler, Tobias; Wagner, Doris; Sahy, Diana; Vadakkepuliyambatta, Sunil; Chand, Shyam; Martma, Tõnu; Kirsimäe, Kalle; Mattingsdal, Rune; Panieri, Giuliana; Bünz, Stefan; Condon, Daniel J.; Knies, Jochen Manfred; Lepland, Aivo (Journal article; Tidsskriftartikkel; Peer reviewed, 2024-03-01)
      The hydrocarbon seepage chronology during deglaciation across the formerly glaciated Barents Sea was established using uranium-thorium (U–Th) dating of seep carbonates. Seep carbonates were sampled with remotely operated vehicles (ROV) from the seafloor at three active hydrocarbon seeps (water depth 156–383 m), located in the north-west (Storfjordrenna), north-central (Storbanken High), and south-west ...
    • Putative fossils of chemotrophic microbes preserved in seep carbonates from Vestnesa Ridge, off northwest Svalbard, Norway 

      Himmler, Tobias; Cremiere, Antoine; Birgel, Daniel; Wirth, Richard; Orphan, Victoria J.; Kirsimae, Kalle; Knies, Jochen; Peckmann, Jörn; Lepland, Aivo (Journal article; Tidsskriftartikkel; Peer reviewed, 2021-10-20)
      The microbial key players at methane seeps are methanotrophic archaea and sulfate-reducing bacteria. They form spherical aggregates and jointly mediate the sulfate-dependent anaerobic oxidation of methane (SD–AOM: CH4 + SO42– → HCO3– + HS– + H2O), thereby inducing the precipitation of authigenic seep carbonates. While seep carbonates constitute valuable archives for molecular fossils of SD–AOM-mediating ...
    • The pyrite multiple sulfur isotope record of the 1.98 Ga Zaonega Formation: Evidence for biogeochemical sulfur cycling in a semi-restricted basin 

      Paiste, Kärt; Pellerin, André; Zerkle, A.L.; Kirsimäe, K.; Prave, A.R.; Romashkin, A.E; Lepland, Aivo (Journal article; Tidsskriftartikkel; Peer reviewed, 2020-01-21)
      The pyrite sulfur isotope record of the 1.98 Ga Zaonega Formation in the Onega Basin, NW Russia, has played a central role in understanding ocean-atmosphere composition and inferring worldwide fluctuations of the seawater sulfate reservoir during the pivotal times of the Paleoproterozoic Era. That, in turn, has led to a concept that Earth's atmospheric oxygen levels underwent global-scale changes. ...
    • Redox fluctuations, trace metal enrichment and phosphogenesis in the ~2.0 Ga Zaonega Formation 

      Kipp, Michael A.; Lepland, Aivo; Buick, Roger (Journal article; Tidsskriftartikkel; Peer reviewed, 2020-03-24)
      The ~2.0 Ga Zaonega Formation (ZF) holds one of the oldest phosphorites in the geologic record, reaching >15% P<sub>2</sub>O<sub>5</sub>. Understanding the depositional conditions that enabled sedimentary phosphorus enrichment in this unit will thus help us to interpret the significance of the temporal distribution of phosphorites in Earth’s early history. Here we use an array of major and trace ...
    • REE+Y uptake and diagenesis in Recent sedimentary apatites 

      Lumiste, Kaarel; Mänd, Kaarel; Bailey, Juke; Paiste, Päärn; Lang, Liisa; Lepland, Aivo; Kirsimäe, Kalle (Journal article; Tidsskriftartikkel; Peer reviewed, 2019-07-30)
      Rare Earth Elements and Yttrium (REE+Y) distribution in authigenic phases are frequently used as proxies for reconstructing past seawater conditions. Sedimentary apatite precipitates near the sediment-water interface and is therefore capable of recording the REE+Y composition of the overlying water column. While the overprinting of primary REE+Y signal during late stage diagenesis is a widely known ...
    • A refined late-Cryogenian – Ediacaran Earth history of South China: phosphorous-rich marbles of the Dabie and Sulu orogens 

      Prave, Anthony R; Meng, F.; Lepland, Aivo; Kirsimäe, Kalle; Kreitsmann, Timmu; Jiang, C.Z. (Journal article; Tidsskriftartikkel; Peer reviewed, 2017-12-02)
      The late-Cryogenian – Ediacaran geological framework for South China is constructed principally from sedimentary successions preserved in the central and western regions of the Yangtze Block. New stratigraphic and carbonate-carbon isotope data allow us to extend that framework into the exhumed HP-UHP subduction complexes of the eastern Dabie and Sulu orogens that separate the South and North China ...
    • Small calcium isotope fractionation at slow precipitation rates in methane seep authigenic carbonates 

      Blättler, Clara L.; Hong, Wei-Li; Kirsimae, Kalle; Higgins, John A.; Lepland, Aivo (Journal article; Tidsskriftartikkel; Peer reviewed, 2021-04-01)
      Natural calcium carbonate minerals express a range of calcium isotope fractionations, with the precipitated mineral typically enriched in the lighter isotopes of calcium relative to source fluids. Experimental and theoretical evidence shows a strong dependence on precipitation rate, although this relationship has not been well quantified over the range of precipitation rates observed in natural ...
    • Sources and turnover of organic carbon and methane in fjord and shelf sediments off Northern Norway 

      Sauer, Simone; Hong, Wei-Li; Knies, Jochen; Lepland, Aivo; Forwick, Matthias; Klug, Martin; Eichinger, Florian; Baranwal, Soma; Cremiere, Antoine; Chand, Shyam; Schubert, Carsten J. (Journal article; Tidsskriftartikkel; Peer reviewed, 2016-10-22)
      To better understand the present and past carbon cycling and transformation processes in methane-influenced fjord and shelf areas of northern Norway, we compared two sediment cores from the Hola trough and from Ullsfjorden. We investigated (1) the organic matter composition and sedimentological characteristics to study the sources of organic carbon (C<sub>org</sub>) and the factors influencing ...
    • Strategy for Detection and High-Resolution Characterization of Authigenic Carbonate Cold Seep Habitats Using Ships and Autonomous Underwater Vehicles on Glacially Influenced Terrain 

      Thorsnes, Terje; Chand, Shyam; Brunstad, Harald; Lepland, Aivo; Lågstad, Petter Arthur (Journal article; Tidsskriftartikkel; Peer reviewed, 2019-11-26)
      Cold seep habitats with authigenic carbonates and associated chemosynthetic communities in glacially influenced terrains constitute an important part of the benthic ecosystems, but they are difficult to detect in large-scale seabed surveys. The areas they occupy are normally small, and survey platforms and sensors allowing high-resolution spatial characterization are necessary. We have developed a ...
    • Timescales of methane seepage on the Norwegian margin following collapse of the Scandinavian Ice Sheet 

      Cremiere, Antoine; Lepland, Aivo; Chand, Shyam; Sahy, Diana; Condon, Daniel J.; Noble, Stephen R.; Martma, Tõnu; Thorsnes, Terje; Sauer, Simone; Brunstad, Harald (Journal article; Tidsskriftartikkel; Peer reviewed, 2016-05-11)
      Gas hydrates stored on continental shelves are susceptible to dissociation triggered by environmental changes. Knowledge of the timescales of gas hydrate dissociation and subsequent methane release are critical in understanding the impact of marine gas hydrates on the ocean–atmosphere system. Here we report a methane efflux chronology from five sites, at depths of 220–400 m, in the southwest Barents ...
    • Two-billion-year-old evaporites capture Earth’s great oxidation 

      Blättler, C.L.; Claire, M.W.; Prave, A.R.; Kirsimäe, K.; Higgins, J.A.; Medvedev, P.V.; Romashkin, A.E; Rychanchik, D.V.; Zerkle, A.L.; Paiste, Kärt; Kreitsmann, T.; Millar, I.L.; Hayles, J.A.; Bao, H.; Turchyn, A.V.; Warke, M.R.; Lepland, Aivo (Journal article; Tidsskriftartikkel; Peer reviewed, 2018-04-20)
      Major changes in atmospheric and ocean chemistry occurred in the Paleoproterozoic era (2.5 to 1.6 billion years ago). Increasing oxidation dramatically changed Earth’s surface, but few quantitative constraints exist on this important transition. This study describes the sedimentology, mineralogy, and geochemistry of a 2-billion-year-old, ~800-meter-thick evaporite succession from the Onega Basin in ...
    • U-Th chronology and formation controls of methane-derived authigenic carbonates from the Hola trough seep area, northern Norway 

      Sauer, Simone; Knies, Jochen; Lepland, Aivo; Sahy, Diana; Martma, Tõnu; Noble, Stephen R.; Schönenbergerb, Jasmin; Klug, Martin; Schubert, Carsten J. (Journal article; Tidsskriftartikkel; Peer reviewed, 2017-10-20)
      We investigated methane-derived authigenic carbonate (MDAC) crusts and nodules from a cold seep site on the northern Norwegian continental shelf in ca. 220 m water depth to determine the timing and mode of their formation. Gas bubbling observed during remotely operated vehicle (ROV)-assisted sampling of MDAC crusts revealed ongoing seep activity. Authigenic carbonates were present as crusts on the ...
    • Variations in gas and water pulses at an Arctic seep: fluid sources and methane transport 

      Hong, Wei-Li; Torres, Marta E.; Portnov, Aleksei D; Waage, Malin; Haley, B.; Lepland, Aivo (Journal article; Tidsskriftartikkel; Peer reviewed, 2018-04-19)
      Methane fluxes into the oceans are largely dependent on the methane phase as it migrates upward through the sediments. Here we document decoupled methane transport by gaseous and aqueous phases in Storfjordrenna (offshore Svalbard) and propose a three‐stage evolution model for active seepage in the region where gas hydrates are present in the shallow subsurface. In a preactive seepage stage, solute ...